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Canon printers never mix pigment black and dye black ink but there are cases where they mix pigment or dye black with dye colors, even when printing just black. In these cases you cannot tell by dripping water on a printout if the pigment black or the dye black is used because there will be running in both cases. And the drip test may not work with some third party inks because many suppliers mix dye black ink in with their pigment black ink. To find out, do a nozzle test on plain paper and see if the grid at the top of the page bleeds when water is dripped on it.
To summarize:
1) Pigment black is never used on any photo paper. Dye black is always used on photo paper.
2) Pigment black is almost always used on plain paper, except (as stratman pointed out earlier) dye black is used when doing borderless printing.
3) Pigment black is the only ink used when printing black (or greyscale) on plain paper except in duplex printing.
4) Pigment black is mixed with dye colors when printing black (or greyscale) on plain paper in duplex printing.
5) Dye black is mixed with other dye colors when printing black (or greyscale) on photo paper.
You can read a lot of discussion on this subject by clicking on the Inkjet FAQ's link at the top of this page.
Keep in mind that these test were done on printers prior to the chip cartridges coming out--I assume that the same holds true for newer printers.
To summarize:
1) Pigment black is never used on any photo paper. Dye black is always used on photo paper.
2) Pigment black is almost always used on plain paper, except (as stratman pointed out earlier) dye black is used when doing borderless printing.
3) Pigment black is the only ink used when printing black (or greyscale) on plain paper except in duplex printing.
4) Pigment black is mixed with dye colors when printing black (or greyscale) on plain paper in duplex printing.
5) Dye black is mixed with other dye colors when printing black (or greyscale) on photo paper.
You can read a lot of discussion on this subject by clicking on the Inkjet FAQ's link at the top of this page.
Keep in mind that these test were done on printers prior to the chip cartridges coming out--I assume that the same holds true for newer printers.